| Cui Tiankai Vice-Minister of the Ministry of Foreign Affairs |
| 1997—1999 | Counselor, Permanent Mission of the PRC to the United Nations | |
| He Yafei Deputy Director of the Overseas Chinese Affairs Office of the State Council |
| 2010—2012 | Ambassador, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| 1994—1996 | Counselor, Permanent Mission of the PRC to the United Nations | |
| 1992—1994 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Baodong Plenipotentiary Ambassador, Chinese Permanent Representative to the United Nations |
| 2010— | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 2006—2010 | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| Li Xinhua Assistant Minister, Ministry of Foreign Affairs |
| 1981—1986 | Attache, 3rd Secretary, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Yong Vice-Minister of the Ministry of Finance |
| 1985—1988 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| 1985—1988 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Zhaoxing Chairman of the Foreign Affairs Committee of the 11th NPC |
| 1993—1995 | Ambassador, Permanent Mission of the PRC to the United Nations | |
| Liu Jieyi Assistant Minister of Foreign Affairs, Deputy Director of the International Liaison Department of the CPC Central Committee |
| 1995—1998 | Counselor, Permanent Mission of the PRC to the United Nations | |
| Long Yongtu Secretary-General, Boao Forum for Asia |
| 1978—1980 | Attache, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 1978—1980 | Third Secretary, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| Lu Xinhua Commissioner of the Commissioner's Office of the Ministry of Foreign Affairs in Hong Kong |
| 1981—1986 | Attache, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Third Secretary, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Shen Guofang Vice-Minister of the Ministry of Foreign Affairs |
| 1998—2002 | Ambassador, Permanent Mission of the PRC to the United Nations | |
| 1998—2002 | Deputy Commissioner, Permanent Mission of the PRC to the United Nations | |
| Wang Guangya Alternate Member of the 17th CPC Central Committee, Director of the Hong Kong and Macao Affairs Office of the State Council |
| 1988—1992 | Counselor, Permanent Mission of the PRC to the United Nations | |
| 1982—1983 | Attache, Permanent Mission of the PRC to the United Nations | |
| 1977—1981 | Staff, Permanent Mission of the PRC to the United Nations | |
| 1977—1981 | Attache, Permanent Mission of the PRC to the United Nations | |
| Wu Jianmin President of China Foreign Affairs University |
| 1989—1990 | Deputy Chief, Permanent Mission of the PRC to the United Nations | |
| Zhang Yesui Plenipotentiary Ambassador to the United States |
| 2008—2010 | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 1988—1992 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| 1988—1992 | Counselor, Permanent Mission of the PRC to the United Nations | |